A brother-in-law of slain BJP leader Pramod Mahajan, Munde hails from a poor family in the backward Marathwada region and was brought into politics by the late BJP leader Vasantrao Bhagwat, who also groomed several other youngsters including Pramod Mahajan. Munde got involved into Politics when he met Pramod Mahajan. As a member of the Akhil Bharatiya Vidyarthi Parishad, he took part in the agitation against the state of emergency imposed by the Prime Minister Indira Gandhi. He was incarcerated in the Nashik central jail until the Emergency was lifted.